Angelina Jolie Means Business In Valentino Shirt And Ballgown Skirt

Angelina Jolie stepped into a Valentino Haute Couture skirt, shirt and blazer ensemble for the UK premiere of 'The Eternals'. Alongside posing alone, the 46 year-old also walked the carpet with her five children.

SHOP VALENTINO NOW

The 46-year-old looked joyful in a leather-look strapless midi dress by Dolce & Gabbana while in Rome doing press for Eternals.

SHOP DOLCE & GABBANA NOW

Jolie wore an Atelier Versace gown made from deadstock chainmail to attend the screening of her film. She brought with her daughters Zahara and Shiloh for the evening.

For Maleficent 2's London premiere, Jolie departed from black to wear this stunning Ralph & Russo custom-made chiffon and tulle hand pleated gown. The dress featured a gold caged bodice, a floor length cape as well as sculptured shoulders decorated with Swarovski crystal spiders.

The mother-of-six wore a vampy Alexander McQueen ensemble during a photocall for Maleficent: Mistress of Evil in London.

The actress wore custom Atelier Versace at the premiere for Maleficent: Mistress of Evil in Rome.

For a photocall in the Italian capital ahead of the premiere, Jolie injected some colour into her promotional tour wardrobe by way of Givenchy SS19 Couture.

For the Japan premiere, where she was reunited with her son Maddox who is at university in South Korea, Jolie opted for sparkly silver, owning the red carpet in this Ralph & Russo flapper-style fringe halter dress.

Jolie kickstarted her Maleficent red carpet looks with this custom Atelier Versace one-shoulder gown, clasped at the waist with a diamond scorpion at the world premiere.

Attending the 2019 Comic Con, where she was announced as the latest actor to star in Marvel's upcoming Eternals film, Angie wore a one-shouldered draped black midi dress by Saint Laurent.

For a Parisian day out with godmother Jacqueline Bisset, Angelina Jolie wore a striped maxi dress by Loro Piana in July 2019.

The actress made a surprise appearance with four of her children at the March 2019 premiere of Dumbo, wearing a white Atelier Versace gown with a sheer overlay.

The actress wore a stunning off-the-shoulder gown by British fashion house Ralph & Russo for the 2018 BAFTAs.

To attend a ceremony at St Paul's Cathedral to mark the 200th anniversary of the Order of Saint Michael and Saint George, of which Angelina was made an honorary Dame by the Queen, in June 2018, the humanitarian wore a grey dress by Ralph & Russo

Angelina Jolie wore a sheer nude gown by Elie Saab with embellished feature detail for the 2018 ASC Awards.

At the 2018 Critics' Choice Awards, Angelina wore a custom-made Ralph & Russo strapless gown with an asymmetric hem and feathered bustier.

The actress wore a silvery grey wrap dress by Jenny Packham, and a Tiffany &Co necklace, at the 2017 Hollywood Film Awards.

Angelina Jolie wore a dusky grey Dior gown to attend the First They Killed My Father New York premiere.

Arriving at a special screening of her new film on September 13, 2017

Angelina walks the red carpet for the Toronto premiere of her film: 'First They Killed My Father: A Daughter of Cambodia Remembers.' She is wearing a Ralph and Russo dress.

Angelina Jolie attends 'The Breadwinner' premiere during the 2017 Toronto International Film Festival on September 10. Angelina is wearing Givenchy with Butani Jewellery earrings.

Chief Content Officer for Netflix Ted Sarandos walks with Angelina as they walk to the premiere of 'First They Killed My Father' at the Telluride film festival in Colorado.

Ange greets former Queen Monique in Cambodia in this beautiful fuschia dress, during the premiere of Jolie's new film 'First They Killed My Father' at the Elephant Terrace inside the Angkor park. February 2017.

Angelina dons a plain black mini-dress for the premiere of 20th Century Fox's 'Kung Fu Panda 3' in January 2016.

Angelina Jolie attends the premiere of 'By the Sea' at the 2015 AFI Fest in this beautiful sparkly Atelier Versace bustier dress.

Angelina Jolie wearing Saint Laurent at the BAFTAs 2014.

Angelina Jolie wearing Ralph & Russo couture dress to the premiere of Unbroken in London, November 2014.

Angelina Jolie wears Versace to the Unbroken Photo Call in Sydney, November 2014.

Angelina wears a Gucci Couture gown to the Unbroken premiere in Sydney, November 2014.

Angelina Jolie is presented with the Insignia of an Honorary Dame Grand Cross of the Most Distinguished Order of St Michael and St George by Queen Elizabeth II, Buckingham Palace, London.

Angelina Jolie wears Michael Kors s/s 2014 ensemble with Jimmy Choo Abel heels to Day 2 of the Global Summit to end Sexual Violence in Conflict.

Angelina Jolie wears all-white Michael Kors s/s 2014 separates with nude Agnes Jimmy Choo heels to the Global Summit to end Sexual Violence in Conflict, London.

Angelina Jolie wears Versace to the World Premiere of Maleficent on May 28th 2014.

Angelina Jolie is seen on Upper East Side wearing Jimmy Choo Agnes heels.

Angelina Jolie wears Ralph Lauren with Christian Louboutin shoes and earrings by Robert Procop at the Maleficent Paris Photocall on May 6th 2014.

Angelina Jolie poses at a photocall for Maleficent at the Corinthia Hotel London.

Angelina Jolie wears custom-made Atelier Versace to a private reception as costumes and props from Disney's Maleficent go on exhibit at Kensington Palace in support of the Great Ormond Street Hospital.

Angelina Jolie in Atelier Versace in 2014.

Angelina Jolie wearing Ralph & Russo.

Angelina Jolie is wearing an Yves Saint Laurent dress to attend the 4th Annual Women in the World Summit, April 2013

Angelina Jolie arrived at the 2012 Golden Globes in a two-tone satin Atelier Versace gown.

The actress wore a long-sleeved, emerald green, crystal covered gown to the 2011 Golden Globes, again by Atelier Versace.

Angelina Jolie in a Jenny Packham AW 2011 gown, Gucci heels, a Louis Vuitton clutch and vintage jewels at the SAG awards, January 2012.

Angelina Jolie in a Gucci chain embellished sateen jacket, at the 3rd Annual Women In The World Summit, New York.

Angelina Jolie arrives for the UK film premiere of 'Salt' at Leicester Square, London on August, 2010. Angelina wears an Amanda Wakeley dress

Angelina Jolie arrives at The Orange British Academy Film Awards held at the Royal Opera House on February 2009 in London

Angelina Jolie arrives at the Los Angeles premiere of 'Inglorious Basterds' at the Grauman's Chinese Theatre on August 10, 2009 in Hollywood. Angelina wears a Michael Kors dress.

Angelina Jolie attends the 'Salt' Los Angeles Premiere at Grauman's Chinese Theatre on July 2010 in Hollywood.

Angelina Jolie arrives at the 81st Academy Awards, February 2009 in Hollywood

Angelina at the 60th Cannes Film Festival, Cannes, May 2007. Angelina wears an Ungaro dress.

Angelina Jolie at the 5th Annual Screen Actors Guild Awards, March 1999.

Angelina Jolie arrives at the Annual Emmy Awards in LA, Sept 1998.